全文获取类型
收费全文 | 1116篇 |
免费 | 59篇 |
国内免费 | 317篇 |
专业分类
安全科学 | 167篇 |
废物处理 | 13篇 |
环保管理 | 151篇 |
综合类 | 557篇 |
基础理论 | 227篇 |
污染及防治 | 205篇 |
评价与监测 | 120篇 |
社会与环境 | 45篇 |
灾害及防治 | 7篇 |
出版年
2024年 | 1篇 |
2023年 | 16篇 |
2022年 | 21篇 |
2021年 | 32篇 |
2020年 | 30篇 |
2019年 | 43篇 |
2018年 | 28篇 |
2017年 | 40篇 |
2016年 | 46篇 |
2015年 | 44篇 |
2014年 | 58篇 |
2013年 | 104篇 |
2012年 | 65篇 |
2011年 | 95篇 |
2010年 | 69篇 |
2009年 | 92篇 |
2008年 | 84篇 |
2007年 | 97篇 |
2006年 | 78篇 |
2005年 | 68篇 |
2004年 | 66篇 |
2003年 | 54篇 |
2002年 | 44篇 |
2001年 | 30篇 |
2000年 | 30篇 |
1999年 | 30篇 |
1998年 | 17篇 |
1997年 | 20篇 |
1996年 | 14篇 |
1995年 | 15篇 |
1994年 | 12篇 |
1993年 | 12篇 |
1992年 | 4篇 |
1991年 | 2篇 |
1990年 | 3篇 |
1989年 | 5篇 |
1988年 | 3篇 |
1987年 | 4篇 |
1986年 | 2篇 |
1985年 | 2篇 |
1984年 | 2篇 |
1983年 | 1篇 |
1981年 | 3篇 |
1978年 | 3篇 |
1977年 | 1篇 |
1974年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有1492条查询结果,搜索用时 300 毫秒
71.
Cr(VI) is far more soluble and toxic than Cr(III). Sediment pore water was investigated in a river adjacent to the property of a large former tannery, into which Cr-contaminated effluent was discharged over a 55-year period, and where extremely high Cr concentrations have been found in the sediments. Dialysis cells, or peepers, were used to generate depth profiles of Cr concentration in sediment pore water. Samples were analyzed for total Cr using inductively coupled plasma-mass spectrometry (ICP-MS) and for Cr species using high performance liquid chromatography (HPLC)-ICP-MS. The results show an absence of Cr(VI) in all samples. Furthermore, incomplete recovery of Cr(VI) added to the samples collected at the locations with highest sediment Cr concentrations indicate strong reducing conditions at those locations, which are not conducive to the presence of Cr(VI). 相似文献
72.
K. Yoshida I. Fuzesi M. Suzan L. Nagy 《Journal of environmental science and health. Part. B》2013,48(2):169-183
Abstract A traditional method to determine operator dermal exposure is to quantify the amount of pesticide coming into contact with specific body regions and then to integrate the deposition density values with the total body surface. It is known that extremely high deposition values may occur in the hand region; however, the source of contamination is generally assumed to be direct splash or contact with the pesticide container. One of the parameters affecting operator/pilot exposure could be the transfer of pesticide residue, particularly in the case of pesticides with a longer half‐life, from contaminated surfaces of spray equipment by direct contact over extended periods. If the rate of skin absorption of pesticide is readily known, the expected values of daily dose for an operator or pilot may significantly rise due to the extended contact period. This study produced field data on the surface contamination of spray equipment used for ground and aerial applications. If field data on precise work practice (time‐motion) observations are incorporated, it may be possible to estimate the potential exposure of operator/pilot due to hand contact with contaminated surfaces. 相似文献
73.
The addition of activated carbon (AC) is an increasingly popular method for pollutant immobilization, and the AC material can be made of biomass or coal/fossil feedstock. The aim of the present study was to investigate whether there are differences between pollutant sorption to biomass and coal-based AC in the presence and absence of sediment. Through N2 and CO2 adsorption to probe surface area and pore size it was shown that the biomass-based AC had a stronger dominance of narrow pores in the size range 3.5-15 Å than the anthracite-based material. In the absence of sediment, sorption isotherms for the probe compounds pyrene and PCB-101 showed stronger sorption for the biomass-based AC (logarithmic Freundlich coefficients 8.15 for pyrene; 9.91 for PCB-101) than for the anthracite-based one (logarithmic Freundlich coefficients 7.20 and 9.70, respectively). In the presence of sediment, the opposite trend was observed, with the stronger sorption for anthracite-based AC. Thus, the presence of competing and/or pore-blocking sediment constituents reduces sorption to a larger extent for biomass-derived AC (factor of 5 for pyrene to almost 100 for PCB-101) than for anthracite-based AC (no reduction for pyrene to factor of 5 for PCB-101). This difference is tentatively attributed to the difference in pore size distribution, narrow pores being more prone to clogging, and could have implications for remediation feasibility with AC from different sources. 相似文献
74.
道路交通噪声自动监测应用探讨 总被引:3,自引:0,他引:3
结合城市道路路网状况及实际噪声监测数据和历史实验数据,对道路交通噪声自动监测数据的有效性、监测点位布设进行了研究,对道路交通噪声监测点位优化提出建议。 相似文献
75.
农药的大量使用污染了大气、水体及生态系统。有机农药以直接施用、拌种、喷撒、随降水落入等方式进入土壤。农药在土壤中会以吸附、扩散稀释和降解等几种方式发生转化,并改变土壤结构、对土壤中生物的生存及酶的活性产生影响。生物修复技术可以通过动植物、微生物及根际环境对农药污染的降解来治理土壤中的农药,是治理农药污染的一种推荐方法。 相似文献
76.
Phytoavailability and geospeciation of cadmium in contaminated soil remediated by Rhodobacter sphaeroides 总被引:1,自引:0,他引:1
A microorganism was isolated from oil field injection water and identified as Rhodobacter sphaeroides. It was used for the remediation of simulated cadmium-contaminated soil. The phytoavailability of Cd was investigated through wheat seedling method to determine the efficiency of remediation. It was found that after remediation, the accumulation of Cd in wheat roots and leaves decreased by 67% and 53%, respectively. The Cd speciation in soil was determined with Tessier extraction procedure. It was found that the total Cd content in soil did not change during the experiments, but the geo-speciation of Cd changed remarkably. Among the five fractions, the concentration of exchangeable phases decreased by 27-46% and that of the phases bound to Fe-Mn oxides increased by 22-44%. The decrease of Cd accumulation in wheat showed significant positive correlation with the decrease of exchangeable phases. It could be concluded that the remediation of R. sphaeroides was carried out through the conversion of Cd to more stable forms. The decrease of sulfate concentration in supernatant indicated that the R. sphaeroides consumed sulfate. 相似文献
77.
Tova Rosenbloom Author Vitae Adar Ben-Eliyahu Author Vitae Author Vitae Ariela Biegel Author Vitae Author Vitae 《Journal of Safety Research》2009,40(3):215-219
Introduction
This article compares observed driving behavior in a city, a town, and a village.Method
Unobtrusive observations were made at intersections in each residential type. Five violation types were observed: (a) not wearing a seat belt (seat belt violation); (b) not using a safety seat for a child (safety seat violation for children); (c) not using a speaker while speaking on the phone (on-phone violation); (d) failing to comply with a ‘give way’ sign (‘give way’ sign violation); and (e) stopping in an undesignated area (undesignated stop violation). It was expected that in accordance with the anonymity hypothesis that the bigger residential areas' rate of traffic violations would be higher. The effects of the residential type, drivers' gender, and age were assessed using the multiple regression model. The stepwise method of evaluation was employed. The model converged on step 3 (Adjusted R square = 0.039). Residential type and gender contributed significantly to the model. Results: Consistent with prior research, male drivers committed more violations than female drivers. Chi-square analyses were used to test the distribution of violations by the settlement types. Overall, more drivers committed violations in the two small residential areas than in the city, with 30% of city drivers, 43% of town drivers, and 51% of village drivers committing at least one violation (χ2 (2) = 37.65, p < 0.001). Moreover, in the town and the village, a combination of one or more violations was committed more often than in the city (χ2 (1) = 34.645, p < 0.001). Accordingly, more drivers committed violations in the two small settlements (48.4%) than in the city (30.6%). Possible explanations for the observed results were provided in the Discussion section.Impact on Industry
The conclusions of this paper are that drivers in small villages tend to disobey traffic laws. Therefore, efforts have to be made in companies to take this issue in consideration while running fleets in companies located in small places far from the center. 相似文献78.
Zora Jandrić Mohammad N. Rathor Sorivan Chhem-Kieth Joseph Adu-Gyamfi Leopold Mayr Christian Resch 《Journal of environmental science and health. Part. B》2013,48(12):1034-1042
Plant uptake of toxins and their translocation to edible plant parts are important processes in the transfer of contaminants into the food chain. Atropine, a highly toxic muscarine receptor antagonist produced by Solanacea species, is found in all plant tissues and can enter the soil and hence be available for uptake by crops. The absorption of atropine and/or its transformation products from soil by wheat (Triticum aestivum var Kronjet) and its distribution to shoots was investigated by growing wheat in soil spiked with unlabeled or 14C-labeled atropine. Radioactivity attributable to 14C-atropine and its transformation products was measurable in plants sampled at 15 d after sowing (DAS) and thereafter until the end of experiment. The highest accumulation of 14C-atropine and/or its transformation products by plants was detected in leaves (between 73 and 90% of the total accumulated) with lower amounts in stems, roots, and seeds (approximately 14%, 9%, and 3%, respectively). 14C-Atropine and/or its transformation products were detected in soil leachate at 30, 60, and 90 DAS and were strongly adsorbed to soil, with 60% of the applied dose adsorbed at 30 DAS, plateauing at 70% from 60 DAS. Unlabeled atropine was detected in shoots 30 DAS at a concentration of 3.9 ± 0.1 μg kg?1 (mean ± SD). The observed bioconcentration factor was 2.3 ± 0.04. The results suggest a potential risk of atropine toxicity to consumers. 相似文献
79.
Abstract The sorption and desorption characteristics of four herbicides (diuron, fluometuron, prometryn and pyrithiobac‐sodium) in three different cotton growing soils of Australia was investigated. Kinetics and equilibrium sorption and desorption isotherms were determined using the batch equilibrium technique. Sorption was rapid (> 80% in 2 h) and sorption equilibrium was achieved within a short period of time (ca 4 h) for all herbicides. Sorption isotherms of the four herbicides were described by Freundlich equation with an r2 value > 0.98. The herbicide sorption as measured by the distribution coefficient (Kd) values ranged from 3.24 to 5.71 L/kg for diuron, 0.44 to 1.13 L/kg for fluometuron, 1.78 to 6.04 L/kg for prometryn and 0.22 to 0.59 L/kg for pyrithiobac‐sodium. Sorption of herbicides was higher in the Moree soil than in Narrabri and Wee Waa soils. When the Kd values were normalised to organic carbon content of the soils (KoC), it suggested that the affinity of the herbicides to the organic carbon increased in the order: pyrithiobac‐sodium < fluometuron < prometryn < diuron. The desorption isotherms were also adequately described by the Freundlich equation. For desorption, all herbicides exhibited hysteresis and the hysteresis was stronger for highly sorbed herbicides (diuron and prometryn) than the weakly sorbed herbicides (fluometuron and pyrithiobac‐sodium). Hysteresis was also quantified as the percentage of sorbed herbicides which is not released during the desorption step ω = [nad / nde ‐1] x 100). Soil type and initial concentration had significant effect on ω. The effect of sorption and desorption properties of these four herbicides on the off‐site transport to contaminate surface and groundwater are also discussed in this paper. 相似文献
80.
Steen Solvang Jensen Tim Larson K.C. Deepti Joel D. Kaufman 《Atmospheric environment (Oxford, England : 1994)》2009,43(30):4544-4556
We evaluated the Danish AirGIS air quality and exposure model system using air quality measurement data from New York City in the Multi-Ethnic Study of Atherosclerosis and Air Pollution (MESA Air). Measurements were used from three US EPA Air Quality System (AQS) monitoring stations and a comprehensive MESA Air measurement campaign including about 150 different locations and about 650 samples of about 2 week measurements of NOx, NO2 and PM2.5. AirGIS is a deterministic exposure model system based on the dispersion models Operational Street Pollution Model (OSPM) and the Urban Background Model (UBM). The UBM model reproduced the annual levels within 1–26% depending on station and pollutant at the three urban background EPA monitor stations, and generally reproduced well the seasonal and diurnal variation. The full model with OSPM and UBM reproduced the MESA Air measurements with a correlation coefficient of r2 = 0.51 for NOx, r2 = 0.28 for NO2 and r2 = 0.73 for PM2.5. 相似文献